General Chemistry Section 18 - Transition Metals and Coordination Chemistry

General Chemistry Section 18 - Transition Metals and Coordination Chemistry
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**It's best to visit us on the web at General Chemistry Lecture Notes

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General Chemistry Lecture Notes -- for a typical eighteenth chapter ("section") of a high school chemistry course (AP, honors, regular) -or- college-level general chemistry course.

Excellent for instructors who like to write out their lecture notes on the board "as they teach"...

SECTION 18 - TRANSITION METALS AND COORDINATION CHEMISTRY

18-1 -- The Importance of Transition Metals

· The d-block Metals

18-2 -- General Properties of Transition Metals

· The Addition of Core Electrons to Inner d-orbitals and f-orbitals

· Chemical Properties and Physical Properties

· The Formation of Ionic Compounds

· Multiple Oxidation States

· Complex Ions and Paramagnetism

18-4 -- Electron Configurations

· The Diagonal Rule

· Oxidation States (Oxidation Numbers)

18-5 -- Ionization Energy Trends

18-5 -- Atomic Radius Trends and Ionic Radius Trends

· The Lanthanide Contraction

18-6 -- Coordination Compounds

· Complex Ions, Ligands, and Counterions

· Paramagnetic Complexes vs. Diamagnetic Complexes

· Oxidation Numbers vs. Coordination Number

· Geometries of Complex Ions (Linear, Tetrahedral, Square Planar, Octahedral)

18-8 -- Ligands (“Coordinate Covalent Bonds”)

· Monodentate Ligands (Unidentate Ligands) and Bidentate Ligands

· The Oxalate Ligand and the Ethylenediamine Ligand

· Polydentate Ligands

· EDTA, a Hexadentate Ligand

· Chelating Ligands (“Chelates”)

18-10 -- Naming Coordination Compounds

· Names of Some Common Ligands

18-12 -- Isomerism of Complex Ions

· Isomers and Types of Isomerism

18-12 -- Structural Isomers

· Coordination Isomerism

· Linkage Isomerism

18-13 -- Stereoisomerism

· Geometrical Isomerism (Cis-Trans Isomers)

· Optical Isomerism

· Enantiomers and Chiral Compounds

18-16 -- Hybridization

· sp Hybridized Complexes (linear)

· sp3 Hybridized Complexes (tetrahedral, square planar)

· d2sp3 Hybridized Complexes (octahedral)

18-16 -- The Crystal Field Model

· Magnetic Properties of Complex Ions

· Ligands as “Negative Point-Charges”

· d-orbital Splitting: the eg Set vs. the t2g Set

18-17 -- Crystal Field Splitting, D

· Strong-Field Case (Large D, Low-Spin)

· Weak-Field Case (Small D, High-Spin)

· Strong-Field Ligands vs. Weak-Field Ligands

18-20 -- Why are Transition Metal Complexes Usually Colored?

· Complimentary Colors

· Ground States vs. Excited States

Total Pages
22 pages
Answer Key
N/A
Teaching Duration
1 Week
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